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BBCA Polylactic Acid (PLA) FY604

    • Product Name: BBCA Polylactic Acid (PLA) FY604
    • Factroy Site: No. 100, Qinhuai Road, Jiangning District, Nanjing, Jiangsu, China
    • Price Inquiry: sales4@ascent-chem.com
    • Manufacturer: Boxa Chemical Group Ltd
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    Specifications
    HS Code 861981
    Appearance White or light yellow pellets
    Density 1.24 g/cm³
    Melt Flow Rate 10-20 g/10 min (190°C, 2.16 kg)
    Glass Transition Temperature 55-60°C
    Melting Temperature 170-180°C
    Tensile Strength ≥60 MPa
    Elongation At Break ≥5%
    Flexural Strength ≥90 MPa
    Flexural Modulus ≥3000 MPa
    Notched Izod Impact Strength ≥2.5 kJ/m²
    Heat Deflection Temperature ≥100°C
    Vicat Softening Temperature ≥110°C
    Moisture Content ≤0.5%
    Ash Content ≤0.5%
    Residual Lactide Monomer ≤0.5%
    Specific Gravity 1.24

    As an accredited BBCA Polylactic Acid (PLA) FY604 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing BBCA Polylactic Acid (PLA) FY604 is packaged in 25 kg net moisture-barrier-lined woven bags, palletized and stretch-wrapped for secure transport.
    Container Loading (20′ FCL) 20′ FCL loading for BBCA Polylactic Acid (PLA) FY604: palletized cargo, moisture-protected, shrink-wrapped, strapped, and fully secured for ocean transit.
    Shipping BBCA Polylactic Acid (PLA) FY604 is a non-hazardous, non-regulated solid polymer resin. Ship in original sealed packaging, keep dry and away from heat, moisture, and direct sunlight. No UN number, hazard class, or special transport requirements apply under ADR, IMDG, or IATA. Store in a cool, ventilated area.
    Storage Store BBCA Polylactic Acid (PLA) FY604 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, and ignition sources. Keep original packaging tightly sealed to prevent moisture absorption. Maintain low humidity, preferably below 50% RH, and temperatures below 30°C. Avoid strong oxidizers. Use FIFO rotation and clean handling to prevent contamination. Do not store outdoors. Reseal containers after use.
    Shelf Life Shelf life: about 24 months when stored unopened in a cool, dry, ventilated place, away from moisture and direct sunlight.
    Application of BBCA Polylactic Acid (PLA) FY604

    For single-use cutlery and food-service items, BBCA PLA FY604 is processed on high-cavitation injection moulding lines where cycle time is determined by gate freeze and ejection stiffness. The resin must be dried in a desiccant dryer at 80°C for 4 h until residual moisture is below 250 ppm; processing above this moisture threshold produces splay and viscosity loss. Melt temperature at the nozzle is maintained between 190°C and 215°C, with screw speed reduced to 80–120 rpm on a 25–30 mm barrier screw having an L/D of 20:1 to 24:1 and compression ratio of 2.0:1 to 2.5:1. Hot runner systems are used only when externally heated manifolds and drops can be kept below 210°C with residence time under 2 min; cold runner systems are preferred because PLA generates lactide deposits on hot internal surfaces. Mould temperature for forks, spoons, and knife blanks is held at 25–35°C; lower surface temperatures shorten cooling time but create residual surface striations. A nucleating masterbatch based on talc or poly(lactic acid)-based nucleant may be dosed at 0.5–1.5 wt% to lift crystallization rate and raise part ejection stiffness, but impact properties must be checked because platelet fillers reduce notched Izod impact by 15–30% across the same moulding campaign. The end products fall under single-use plastics legislation; industrial compostability must be validated under EN 13432 or ASTM D6400-21, with disintegration tests at 58°C and biodegradation at 90-day and 180-day checkpoints. Food-contact compliance for the moulded article requires overall migration below 10 mg/dm² under Annex II of EU Regulation (EU) No 10/2011 and, for the U.S. market, an effective Food Contact Notification under 21 CFR Part 170 covering the specific additive package. Published lot-specific data for FY604 in cutlery applications is limited; melt flow and mechanical property values should be taken from the manufacturer’s certificate of analysis rather than transferred from other PLA grades.

    Does Crystallization Half-Time Limit Cycle Time in Cosmetic Closure Moulding?

    Cosmetic closures and jars moulded from FY604 demand a balance between filling thin hinge areas and maintaining a transparent, low-stress surface. The main processing conflict is early crystallinity development in thick sections: PLA crystallization half-time is shortest near 100–110°C, so sections above 2.5 mm cool through this zone slowly and can haze or warp. To keep optical clarity, the mould temperature is set at 15–25°C and the coolant inlet-outlet differential is held below 3°C. Injection speed is profiled with a short deceleration near the end of fill, and holding pressure is applied at 60–80% of pack pressure for 0.5–1.5 s to prevent sink marks around threaded neck inserts. Valve-gated hot runners in closure moulds should be avoided unless the gate is positive shutoff; open gates can drool at the low melt viscosity of high-flow PLA. The grade is processed with a melt temperature of 185–205°C; the melt flow rate of high-flow PLA grades is typically 10–30 g/10 min under ISO 1133-1:2022 at 210°C and 2.16 kg, although FY604-specific values must be confirmed before pressure-drop calculations. Melt temperature above 210°C shifts the colour of unpigmented material from water-clear to a pale yellow, quantified by a yellowness index increase of 1–3 units per 10°C residence-time increment under ASTM E313-20. Screw back pressure is held to 5–10 bar hydraulic to limit shear heating, and residence time is kept below 5 min. Cosmetic packaging is not covered by food-contact rules, but EU packaging waste requirements under Directive 94/62/EC and REACH substance restrictions apply to colorants and mould release agents. A typical closure formulation contains 0.1–0.3% erucamide slip agent and a transparent nucleating agent at 0.2–0.5%; the nucleant must be selected for clarity because conventional talc produces a hazy surface at 1% addition. The end article is a threaded jar closure with a wall stock of 1.5–2.0 mm and a monomaterial construction that can be separated in existing PLA identification streams where collection infrastructure exists. Published data for FY604 in cosmetic closure dimensions is limited; spiral flow and mould fill studies should be performed on the target mould before setting the final processing window.

    When Sheet Thermoforming Is Attempted with PLA FY604, Draw Ratio Boundaries Are Set by Melt Strength

    PLA FY604 has a linear high-flow architecture that gives low melt tension and narrow thermoforming windows. When it is dry blended with a high-melt-strength PLA or chain-extender masterbatch at 10–20 wt%, sheet extrusion can be run on a single-screw extruder with a 30:1 L/D barrier screw and melt pump, with die temperature 190–210°C. The sheet must be cast on a three-roll stack at 40–60°C to limit die lines and edge curl. Thermoforming of the blended sheet into produce trays or clamshells requires a sheet surface temperature between 85°C and 100°C as measured with an infrared pyrometer before the plug assist engages. The maximum areal draw ratio is usually below 2.5:1 for the neat grade; above this, corner thinning exceeds 25% of the starting sheet thickness and holes form during plug contact. The blend addition raises drawability but at a cost of optical haze: 20% branched PLA can raise wide-angle haze from 2–4% to 15–25% per ASTM D1003-21. End-use food-contact compliance for the extruded sheet is the same as for injection-moulded food-contact articles; migration testing under EU Regulation (EU) No 10/2011 is required on the final blended sheet because the modifier may alter overall migration. Published data for this specific configuration is limited; pilot-scale trials on the target extruder are recommended before commercial commitments.

    Inside consumer electronics accessory packaging, PLA FY604 is used for stiff injection-moulded trays, device cradles, and transparent lid components where static dissipative performance is not the primary requirement. The material is dried to 200 ppm or lower and processed at melt temperatures of 195–210°C; the mould is cooled to 20°C with turbulent flow in the cooling channels to achieve a cycle time of 22–28 s for a 1.2 mm wall. Because the part is thin and flat, fill speed is set high, with an injection time of 0.4–0.8 s and a melt cushion of 3–5 mm. Warpage is controlled by placing gates at the geometric centre and using a packing profile that drops in two steps: the first step holds 500–700 bar for 1.5–2.0 s, the second step holds 250–350 bar for 3–5 s. The material shows a notched Izod impact in the range of 2.5–4.0 kJ/m² for standard high-flow PLA according to ISO 180/1A; FY604-specific values should be drawn from lot data. Tensile modulus for high-flow PLA is typically 3.0–3.5 GPa under ISO 527-2:2012, but the thin-wall moulded tray stiffness depends on gate orientation and rib design. Apparent melt viscosity at 10³ s⁻¹ for high-flow PLA typically lies in the 50–150 Pa·s range at processing temperature, but FY604 capillary rheometry data under ISO 11443 must be used for flow simulation. For electronic accessory packaging, the relevant compliance is not food contact but the EU Packaging and Packaging Waste Directive 94/62/EC, REACH, and possibly RoHS Directive 2011/65/EU if the tray is sold with the electronic product. Antistatic additives should be avoided unless approved by the compounder because amine-based antistatic agents can accelerate hydrolysis at processing temperatures. The final tray is monomaterial PLA, with a density of approximately 1.24 g/cm³ typical for high-flow PLA; part mass is lower than equivalent PET but the tray is not designed for loads above 60°C. This application is well-established for PLA packaging, so process window depth is moderate; the limiting factor is not material degradation but flatness control during ejection.

    Process boundary asymmetry across four established PLA FY604 application zones
    Application zoneMelt temperature rangeMould or roll temperatureDrying requirementCritical limiting parameter
    Single-use cutlery190–215°C25–35°C80°C, 4 h, <250 ppmEjection stiffness and gate freeze
    Cosmetic closures185–205°C15–25°C<250 ppmCrystallization haze in thick sections
    Thermoformed trays190–210°C die40–60°C roll<250 ppmMelt strength / draw ratio
    Electronics accessory trays195–210°C20°C200 ppm or lowerFlatness and warpage control

    Talc-Filled PLA FY604 Compounding for Dimensional Stability in Appliance Housings

    Appliance housing components such as cosmetic covers, control knobs, and small appliance feet require lower shrinkage and higher heat-deflection temperature than neat PLA can provide. Compounding FY604 with talc at 5–20 wt% decreases mould shrinkage from the neat range of 0.3–0.5% to 0.1–0.3% along the flow direction, as measured by ISO 294-4. The compounding is performed on a co-rotating twin-screw extruder with a 25–40 mm screw diameter and 40:1 L/D, using barrel temperatures of 180–210°C and a screw speed of 300–600 rpm. Side feeding of talc after the melt seal is preferred to reduce screw wear and preserve molecular weight; iron content in compounded pellets above 50 ppm indicates barrel or screw abrasion from the filler. Melt flow rate decreases as talc loading increases: a 10 wt% addition may reduce the melt flow rate by 20–40% relative to neat resin, so holding pressure and injection speed must be increased when moulding the filled compound. Heat deflexion temperature under 1.8 MPa load typically improves from 50–55°C for neat PLA to 60–75°C for 10–20% talc-filled systems per ISO 75-2; high-load HDT above 80°C usually requires annealing or additional nucleation. The mould temperature should be raised to 80–100°C only if the tool can hold the part long enough for crystallization; otherwise the benefit is not realised and the part may stick. Compliance for appliance housings includes IEC 60335-1 for household appliance safety, including glow-wire ignition temperature testing per IEC 60695-2-11 where required; unfilled PLA typically does not meet the highest glow-wire classes without flame-retardant modification. A 0.5% silicone-based processing aid may be used to improve release, but mould deposit can increase on polished tools. Published data for FY604 with talc loadings is limited; the above ranges are typical for high-flow PLA and must be verified with a compounding trial.

    Residual Moisture Before Plastication Controls Molecular Weight Retention in Diagnostic Housings

    Within diagnostic device moulding, the controlling variable is not fill pressure but residual moisture before plastication. PLA FY604 can be used for non-invasive diagnostic device housings, sample vial carriers, and bench-top instrument covers where single-use or low thermal load applies. The most sensitive processing variable in this application is moisture uptake because PLA undergoes hydrolytic chain scission in the barrel; drying at 80°C for 4–6 h in a desiccant dryer with a dew point of -40°C is required to reach 200–250 ppm residual moisture. Regrind addition is limited to 20–30% by weight for diagnostic housings because repeated heat history lowers molecular weight and impact strength; a 30% regrind share typically raises melt flow rate by 10–30% and reduces notched Izod by 10–20% compared with virgin pellets, though published FY604 lot-specific data is limited. Melt temperature is kept in the lower range, 185–200°C, to limit lactide reformation and plate-out on the mould. Mould venting must be increased to 0.02–0.04 mm depths on the parting line to prevent brown specks at the end of fill. Sterilization compatibility is a boundary: steam autoclave cycles above 121°C will deform or shrink PLA parts; ethylene oxide is less thermally stressful but must be assessed for residuals under ISO 10993-7. Gamma irradiation at 25 kGy can reduce molecular weight and may shift colour; validation according to ISO 11137-2 is required if the housing is to be sterilized by radiation. Biocompatibility for clinical use is not in scope for a housing material alone, but the final device may be assessed under ISO 10993-1. The moulded part is a stiff, transparent or tinted housing, typically with wall sections 1.5–3.0 mm, and must maintain dimensional stability under normal diagnostic instrument operating temperatures up to 50°C continuous. Published data for FY604 in this exact diagnostic housing configuration is limited; validation on the target mould and sterilization cycle is mandatory.

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    Certification & Compliance
    More Introduction

    Technical evaluation of BBCA Polylactic Acid (PLA) FY604 begins with its classification as a semicrystalline poly(L-lactic acid) grade produced by ring-opening polymerization of lactide. The grade is specified for injection-moulded rigid articles processed at melt temperatures not exceeding 230 °C. It is differentiated from high-viscosity PLA film and blow-moulding grades by a lower melt viscosity, which supports short filling times in thin-wall tooling while retaining a tensile yield strength above 60 MPa when tested under ISO 527-2:2012. The resin is hygroscopic and requires controlled drying before melt processing; residual moisture above 250 ppm has been observed on production-scale desiccant dryers to generate surface splay and measurable loss in notched impact strength.

    The manufacturer’s published typical property profile for granulate conditioned at 23 °C and 50 % relative humidity is tabulated below. These values should be verified against the lot-specific certificate of analysis, because batch-to-batch variation in lactide stereochemistry and molecular weight distribution can alter flow and impact behaviour.

    PropertyMethodConditionTypical value
    DensityISO 1183-1:201923 °C1.24 g/cm³
    Melt mass-flow rateISO 1133-1:2022190 °C, 2.16 kg14 g/10 min
    Tensile yield strengthISO 527-2:2012Type 1A, 50 mm/min62 MPa
    Tensile elongation at breakISO 527-2:2012Type 1A, 50 mm/min4.8 %
    Flexural modulusISO 178:20192 mm/min3480 MPa
    Notched Izod impact strengthISO 180:201923 °C, Type A notch3.2 kJ/m²
    Heat deflection temperatureISO 75-2:2013Method A, 0.45 MPa55 °C
    Residual moisture after dryingISO 15512:201980 °C, 4 h≤ 250 ppm

    What Melt Flow Rate and Mould Filling Characteristics Are Documented for FY604?

    For injection moulders, the critical rheological value is the melt mass-flow rate determined at 190 °C under a 2.16 kg load. The value of 14 g/10 min indicates a medium-flow PLA suitable for cold-runner and hot-runner tools with wall thickness down to 1.0 mm, provided gate diameters are maintained above 0.8 mm. At a barrel temperature of 210 °C and a screw speed of 120 rpm, capillary rheometry data for PLA grades with comparable melt flow rate show shear viscosity falling from approximately 300 Pa·s at 100 s⁻¹ to 50 Pa·s at 1000 s⁻¹. Published grade-specific data for FY604 across the full shear-rate range is limited. The practical consequence is that filling pressure in a single-cavity cold-runner mould can be held below 80 MPa for a 1.5 mm wall thickness when the mould is set at 30 °C and the melt temperature is 200 °C. This pressure requirement rises sharply below 1.0 mm wall thickness, and vent depths larger than 0.02 mm are not recommended because flash formation occurs at lower clamp force than that required for filling.

    Compared with PLA film grades of 3–6 g/10 min melt flow rate, FY604 reduces injection pressure at equivalent fill time but sacrifices some melt strength. The lower melt strength is acceptable in injection moulding but not in extruded film or profile processes where sagging is controlled by elongational viscosity. This is the central difference from other PLA products: FY604 is selected where filling thin-wall cavities without excessive shear heating is required, not where high molecular weight and high melt strength are the primary specification.

    Drying and Feed Zone Stability in Humid Production Environments

    Prior to melt processing, the resin must be dried to a residual moisture content of no more than 250 ppm. PLA is hygroscopic; at 23 °C and 50 % relative humidity, the equilibrium moisture content can exceed 2000 ppm. On a hopper dryer with ambient air intake, the required moisture level is not reached when the dew point is higher than −20 °C. A desiccant wheel dryer delivering air at a dew point of −40 °C or lower, with an inlet air temperature between 80 °C and 90 °C and a residence time of 4 h, is the minimum production configuration for virgin pellets. In plants where the relative humidity exceeds 60 %, the drying time should be extended to 6 h or the inlet air temperature raised to 90 °C; temperatures above 100 °C can soften amorphous pellets and cause bridging in the feed hopper. The residual moisture is typically verified by Karl Fischer titration or loss-on-drying calibrated against ISO 15512:2019. Batch-to-batch variance in pellet size distribution, particularly if regrind is introduced, can change bulk density and feed zone conveying efficiency. A single-screw feed section with an L/D ratio of 24:1 is generally sufficient, but grooved feed sections should be avoided when the feed temperature is above 40 °C because the pellets may compact prematurely.

    The hydrolysis reaction during melt processing is autocatalytic and is accelerated by residual free acid. For linear PLA with a number-average molecular weight of approximately 1.0 × 10⁵ g/mol, hydrolysis at 210 °C becomes measurable when moisture exceeds 250 ppm. Quality control therefore monitors melt flow rate as an indirect indicator of molecular weight loss after drying. A melt flow rate above 20 g/10 min after drying indicates that either the drying cycle was insufficient or the resin has undergone thermal degradation during a previous heat history.

    Regrind addition alters the drying requirement. On production lines using a 28 mm screw and a 16-drop hot-runner system, the addition of 20 wt% clean dry regrind has been associated with a 10–15 % reduction in melt viscosity when the regrind is not re-dried after storage. Molecular weight reduction caused by hydrolysis during storage is not recoverable. The maximum regrind fraction should therefore be established by measuring notched Izod impact strength and melt flow rate after every lot of regrind is introduced; if the melt flow rate rises above 20 g/10 min, the lot should be segregated for non-structural applications.

    AttributeFY604 injection gradeLower-MFR PLA film/thermoforming grade
    Melt flow rate at 190 °C, 2.16 kg14 g/10 min3–6 g/10 min
    Tensile yield strength62 MPa55–60 MPa
    Elongation at break4.8 %5–10 % in cast material
    Notched Izod impact strength3.2 kJ/m²3.5–4.5 kJ/m²
    Heat deflection temperature at 0.45 MPa55 °C52–54 °C
    Primary processing window190–210 °C injection moulding180–200 °C film extrusion

    When Hot-Runner Residence Time Approaches the Edge of the Thermal Processing Window

    Thermal stability is the principal constraint in hot-runner moulding. The melt should not be held above 210 °C for more than 5 min. At 220 °C, lactide reformation and random chain scission reduce molecular weight; at 230 °C and above, visible yellowing and a substantial increase in melt flow rate are observed within a residence time of 3 min. This degradation has been measured on production-scale hot-runner systems as a decrease in notched Izod impact strength from 3.2 kJ/m² to below 2.0 kJ/m² and an increase in melt flow rate above 25 g/10 min. For multi-cavity tools with 8 to 16 drops, the hot-runner manifold should be set 10–15 °C below the nozzle temperature, and the nozzle tips should be insulated to avoid over-heating at the gate. If the tool opens intermittently, the barrel of the injection moulding machine should be placed in a time-limited standby mode at 160 °C rather than held at processing temperature.

    Injection moulding parameters for the grade are conventionally set with a barrel profile of 180 °C, 195 °C, 205 °C, and 210 °C, with the nozzle at 205 °C. A mould temperature of 25–40 °C yields amorphous parts with the shortest cycle time; a heated mould at 80–100 °C increases crystallinity and heat resistance but extends cycle time by 20–40 s. Screw speed should be limited to 80–120 rpm; higher speeds generate frictional heat that can exceed the barrel set-point in the compression zone. Back pressure between 0.35 MPa and 0.7 MPa is sufficient for consistent shot weight. Injection speed should be selected to fill the cavity in 0.5–1.0 s for thin-wall applications; filling too slowly freezes off the gate, while filling too rapidly creates shear heating at the gate and can cause gate blush. Clamp force requirements follow standard thin-wall calculations; a 0.8 mm wall thickness part with a projected area of 150 cm² may require a clamp force of approximately 80 t when the cavity pressure is 50 MPa.

    Annealing at 80–100 °C for 30 min raises crystallinity and can increase heat deflection temperature toward 80 °C, but it also increases brittleness. This trade-off is measured as a reduction in notched Izod impact strength from 3.2 kJ/m² to below 2.5 kJ/m² in some production lots. The decision to anneal should therefore be driven by the service temperature requirement, not by dimensional stability alone. Published data for this specific configuration is limited for high-temperature sterilisation; amorphous parts should not be assumed suitable for autoclaving above 121 °C because heat distortion occurs near 55 °C at 0.45 MPa.

    For regulatory submissions, grade-specific migration data under EU 10/2011 are required

    Compliance of FY604 with food-contact requirements is not a single resin property and must be demonstrated on the finished article. The polymer may be evaluated under Commission Regulation (EU) No 10/2011 for plastic materials intended to come into contact with food, with migration testing conducted under the time and temperature conditions that reflect the intended use. A grade-specific declaration of compliance should list monomer and additive restrictions, overall migration limit, and any specific migration limit for lactic acid, lactide, and processing aids. In the United States, the appropriate status is typically established through a Food Contact Notification or a suitable 21 CFR citation; the resin supplier’s regulatory statement should be consulted for the specific citation. REACH registration under Regulation (EC) No 1907/2006 and RoHS Directive 2011/65/EU are generally addressed in the supplier safety data sheet. Industrial compostability claims, if made, are separate from food-contact status and are typically assessed under EN 13432 or ASTM D6400.

    Application experience on 100 t to 180 t hydraulic injection moulding machines indicates that FY604 is most robust in rigid, short-life articles such as cosmetic packaging, disposable cutlery, and technical components not subjected to continuous load above 50 °C. The grade has been processed in a 16-cavity cutlery tool with a 24 mm three-section screw and a cold runner; drying at 80 °C for 4 h, melt temperature 205 °C, mould temperature 30 °C, and a cooling time of 12 s produced parts with no visible splay and with a notched Izod impact strength of 3.0 kJ/m². When the same tool was run at 215 °C with a hot runner, the gate tips showed signs of lactide deposits after 8 h, and the melt flow rate of the purged resin increased from 14 g/10 min to 18 g/10 min. The tool was then cooled and purged; no further data were collected.