| HS Code | 471256 |
| Density | 1.24 g/cm³ |
| Melt Flow Rate | 30 g/10 min at 190°C/2.16 kg |
| Tensile Strength At Yield | 62 MPa |
| Tensile Strength At Break | 48 MPa |
| Tensile Modulus | 3.3 GPa |
| Tensile Elongation At Break | 3.5% |
| Flexural Strength | 108 MPa |
| Flexural Modulus | 3.4 GPa |
| Notched Izod Impact Strength | 16 J/m |
| Rockwell Hardness | 88 |
| Heat Deflection Temperature | 55°C at 0.45 MPa |
| Vicat Softening Temperature | 60°C |
| Glass Transition Temperature | 55-60°C |
| Melting Temperature | 155-170°C |
| Clarity | Transparent |
| Renewable Content | 100% |
As an accredited Ingeo Polylactic Acid (PLA) 3251D factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Ingeo Polylactic Acid (PLA) 3251D is supplied in 25 kg moisture-barrier bags, palletized and shrink-wrapped; each pallet holds 1,000 kg. |
| Container Loading (20′ FCL) | Ingeo PLA 3251D loaded in 20′ FCL: 25 kg bags on pallets, shrink-wrapped, secured for transport; dry container, ambient conditions. |
| Shipping | Ingeo PLA 3251D is shipped as non-hazardous thermoplastic resin pellets. It is packaged in moisture-barrier bags, boxes, or octabins. Transport in clean, dry vehicles at moderate temperatures, avoiding excessive heat, moisture, and direct sunlight. No special DOT, IMDG, or IATA hazard classification is required. |
| Storage | Store Ingeo Polylactic Acid (PLA) 3251D in a cool, dry, well-ventilated area, preferably at 10–30°C with low humidity. Keep containers tightly closed to prevent moisture absorption. Protect from direct sunlight, heat, ignition sources, and oxidizers. Avoid prolonged storage above 50°C. Reseal opened packages promptly. Maintain clean, segregated conditions away from incompatible substances. Rotate stock and follow supplier recommendations. |
| Shelf Life | Ingeo PLA 3251D typically has a 12-month shelf life when stored unopened in cool, dry conditions, protected from moisture and heat. |
For thin-wall transparent food packaging tools with nominal wall stock between 0.4 mm and 0.8 mm, Ingeo 3251D is processed on high-speed accumulator-assisted injection molding machines equipped with a general-purpose screw of 20:1 L/D and a compression ratio between 2.5:1 and 3.0:1. The resin is dried in a desiccant dryer delivering air at a dew point of -40 °C or lower, at 80 °C for 4 h, to a moisture target below 250 ppm. If moisture exceeds this threshold, melt-phase hydrolysis lowers molecular weight, raises the melt mass-flow rate unpredictably, and generates splay, silver streaking, and sidewall embrittlement on the molding line. Melt temperature is maintained between 210 °C and 230 °C; residence time at the upper end is minimized because lactide formation and discoloration accelerate above 230 °C. Mold temperature is set at 15 °C to 40 °C for amorphous transparency and rapid ejection. Filling velocities in the range of 150 mm/s to 300 mm/s are required for multicavity tools with valve-gated hot runners; transfer to hold occurs at 95–99% of complete fill, with hold pressure between 60 MPa and 100 MPa. The grade’s high flow, measured per ASTM D1238-20 at 30–40 g/10 min under a 2.16 kg load at 210 °C, enables filling of thin sections without excessive injection pressure, but its low thermal conductivity can produce contact-layer orientation differences and warping if cooling is not uniform. Compliance is evaluated under Regulation (EU) No 10/2011 as amended and the applicable U.S. FDA Food Contact Notification for Ingeo resins, including FCN 000178; mechanical acceptance is measured via ISO 527-2:2012 tensile yield near 60 MPa and ISO 178:2019 flexural modulus near 3,500 MPa. Formulation additions are restricted to a PLA-based colour masterbatch at 2–4 wt% and a slip/antiblock masterbatch at 0.5–1.0 wt% for denesting and ejection; loadings above 5 wt% colour or above 1.5 wt% slip affect gate freeze-off and weld-line position. Terminal product types include dairy cups, portion cups, deli containers, and transparent snap-on lids.
The principal constraint in cutlery tooling is the brittle fracture behavior of neat Ingeo 3251D rather than its ability to fill fork tine ends. Unmodified resin has a notched Izod impact value near 16 J/m under ASTM D256 and a tensile strain at break below 5% under ISO 527-2:2012, which means knife serrations, fork tines, and spoon rim edges can crack during demolding if the part is ejected before the surface skin has solidified. Injection molders therefore position this grade for cold-service, single-use utensils only; hot-food utensils require a higher-heat PLA grade or post-mold annealing, and continuous load-bearing service above 45 °C is not recommended. When fracture resistance must be improved, a biodegradable copolyester impact modifier is incorporated at 10–20 wt%; this reduces clarity and slightly increases viscosity, so melt temperature is lowered to 200–220 °C to preserve molecular weight. Colour masterbatch in cutlery is limited to 2–3 wt% because higher loadings create pigment aggregation at the knit line near the fork crotch. The process uses mold temperatures of 15–30 °C, vent depths of 0.02 mm to 0.04 mm, and injection velocities above 200 mm/s to prevent flow hesitation at the tine ends; hold pressure is set between 60 MPa and 90 MPa, with a clamp force requirement calculated from the projected area of the tool because the high-flow grade can flash if the tool is not fully supported. Compliance for cutlery includes Regulation (EU) No 10/2011 and FDA FCN 000178 for food contact, EN 13432 for industrial compostability claims where applicable, and mechanical testing under ASTM D256 or ISO 180. Terminal products include spoons, forks, sporks, stirrers, and cold-service sampling utensils.
Thick-walled cosmetic jar bodies and closure shells with nominal wall thickness from 2.0 mm to 4.0 mm are molded in multicavity cold-runner tools with pneumatically actuated ejectors for flat-bottomed parts. The processing speed advantage of 3251D is less dominant in thick sections because the limiting step is packing and cooling, not cavity filling. Melt temperature is set between 205 °C and 225 °C, mold temperature between 20 °C and 35 °C, and hold pressure between 70 MPa and 110 MPa. Packing time is extended to 2–4 s per mm of nominal wall to compensate for the high volumetric shrinkage of PLA and to avoid vacuum voids or sink marks on the outer cosmetic surface. Hot runner systems with valve gates are used for closure bodies to minimize gate vestige, but cold runner direct-gate tools are still used for heavy-walled jar bases when gate freeze-off is delayed. The main field-observed failure in this application is gate blush and visible flow hesitation lines on the sidewall, caused by premature cooling when injection velocity is too low; therefore, fill speed above 100 mm/s is maintained even for thick sections. Material for cosmetic containers is normally formulated with 1–3 wt% PLA-based pigment masterbatch and, when UV exposure is possible, 0.1–0.2 wt% of a PLA-compatible UV absorber; no plasticizer is used because it reduces surface hardness and print adhesion. Compliance is addressed through Regulation (EC) No 1907/2006 (REACH), Regulation (EC) No 1223/2009 for finished cosmetic product safety, and RoHS Directive 2011/65/EU for restricted substances. Terminal product types include jar bodies, caps, compact case bases, and non-air-contact components of beauty accessories. The upper service temperature limitation is relevant: these parts must not be subjected to hot-fill or dishwasher conditions above 45 °C.
Ingeo 3251D is molded in consumer goods tools with multicavity layouts and automatic part removal when full transparency and high surface finish are required for desk accessories, comb bodies, and short-cycle houseware components. The grade is processed at melt temperature between 200 °C and 215 °C and mold temperature between 25 °C and 50 °C; mold temperatures at the upper end are used only with highly polished tool surfaces and forced air ejection assist because amorphous PLA can stick to hot steel. Desktop-type parts typically have nominal wall thickness of 1.0 mm to 2.5 mm, so a standard hydraulic injection unit is sufficient; clamping force is calculated at 3–5 kN/cm² of projected area. Drying before molding is performed under desiccant conditions at 80 °C for 4 h, but the opened hopper residence time must be limited in high-humidity plants because PLA regains moisture rapidly. The addition ratio for colour is 2–4 wt% PLA-based masterbatch; an antistatic masterbatch at 0.2–0.5 wt% is used only where dust attraction is operationally unacceptable, because antistatic packages can reduce transparency slightly. Mechanical acceptance includes tensile properties under ISO 527-2:2012 and flexural properties under ISO 178:2019; dimensional stability is checked by ASTM D955-08 mold shrinkage, which for this grade falls in the range of 0.003–0.005 mm/mm. Product-specific compliance includes REACH and RoHS Directive 2011/65/EU; if the component is intended for children’s use, migration limits under EN 71-3 must be applied. This application is not suitable for parts requiring continuous hot-water exposure or high impact resistance, because the notched Izod value near 16 J/m under ASTM D256 is lower than that of polycarbonate or ABS. Terminal products include transparent desk organizers, comb bodies, mirror frames, stationery components, and short-run promotional giveaways.
If a molder positions 3251D as a replacement for general-purpose polystyrene in short-run display components, the main process conflict is the difference in solidification rate and the risk of internal stress in flat rectangular parts with abrupt thickness changes. The grade is molded at melt temperature 200–215 °C and mold temperature 25–40 °C, with injection velocity between 80 mm/s and 120 mm/s for flat parts and holding pressure between 50 MPa and 80 MPa. The melt mass-flow rate of 30–40 g/10 min per ASTM D1238-20 allows filling of long flow paths but also causes hesitation at flow-leader transitions, producing visible stress whitening at the gate and residual stress that becomes apparent when the part is flexed during retail assembly. To reduce this failure mode, the gate is placed in the centre of the part rather than at the edge, and the runner diameter is increased by 10–20% relative to polystyrene tooling to lower shear heating. Colour masterbatch is added at 1–3 wt%; loadings above 3 wt% are avoided because pigment-induced nucleating effects produce haze in flat sections. Compliance for short-run display parts is addressed under REACH and RoHS 2011/65/EU; flammability is not implied and the grade should not be used near unshielded heat sources. Heat deflection temperature is evaluated under ASTM D648 at 0.45 MPa, with published values around 55 °C; therefore, display components must not be placed in direct sunlight behind enclosed glazing. Terminal product types include non-load-bearing display risers, signage clips, badge holders, event-specific trays, and temporary retail furniture parts.
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The Ingeo Polylactic Acid (PLA) 3251D resin is a high-flow, general-purpose injection moulding grade within the NatureWorks bio-based polyester portfolio. It is supplied as a transparent pellet, with a specific gravity reported at 1.24 under ASTM D792-20 and a nominal melt flow rate of 80 g/10 min at 210°C/2.16 kg under ASTM D1238-23 Procedure A. These two values define the primary processing identity of the grade: the resin is intended for injection moulding applications where thin-wall channels, long flow lengths, or multi-cavity tools create high pressure demand at the screw tip. Manufacturer-published data for dry, injection-moulded specimens place tensile yield strength at 60 MPa and notched Izod impact strength at 16 J/m. The high melt-flow position of 3251D differentiates it from low-flow Ingeo injection moulding grades, with only minor differences in room-temperature mechanical strength, and this distinction is central to material substitution decisions.
The data below are typical manufacturer-published values for unreinforced, dry, injection-moulded specimens. They are not minimum or maximum product specification limits. Values are reported under the indicated test method and are subject to lot-to-lot variability associated with polymerization and pellet handling.
| Property | Typical Value | Test Method |
|---|---|---|
| Specific gravity | 1.24 | ASTM D792-20 |
| Melt flow rate at 210°C/2.16 kg | 80 g/10 min | ASTM D1238-23 Procedure A |
| Tensile yield strength | 60 MPa | ASTM D638-14 |
| Tensile elongation at break | 3.5% | ASTM D638-14 |
| Flexural strength | 83 MPa | ASTM D790-17 |
| Flexural modulus | 3.6 GPa | ASTM D790-17 |
| Notched Izod impact strength | 16 J/m | ASTM D256-10 |
| Heat deflection temperature at 0.45 MPa | 55°C | ASTM D648-18 |
| Heat deflection temperature at 1.82 MPa | 50°C | ASTM D648-18 |
| Light transmission | 90% | ASTM D1003-13 |
| Haze | 2% | ASTM D1003-13 |
The thermal values of 55°C at 0.45 MPa and 50°C at 1.82 MPa place 3251D in the same heat-resistance class as other unmodified PLA injection moulding grades. Optical values of 90% transmission and 2% haze support transparent applications when the tool surface is adequately polished and the melt is not subjected to prolonged residence. The combination of a high melt flow rate and unchanged tensile yield indicates that flow enhancement is not obtained through a copolymerized flexibilizing comonomer or an impact-modifier dispersion. Instead, the grade’s rheology reflects a molecular-weight or chain-architecture adjustment that lowers melt viscosity.
Desiccant drying governs the reliability of the resin in the hopper. Following manufacturer-published drying guidance for Ingeo injection moulding grades, 3251D should be dried at 80°C for 4 h in a desiccant dryer to a residual moisture target of <250 ppm. Hydrolytic molecular weight loss accelerates when the moisture content exceeds this threshold; the failure mode in processing is not a sudden melt-temperature shift but a progressive loss of melt strength, increased screw drool, splay on the part surface, and weak weld lines. When the surrounding plant environment exceeds 50% relative humidity, open storage time after drying should be regarded as operationally limited. The preferred arrangement under such conditions is a closed hopper feeder connected to a dry-air conveying system. Published data for the exact moisture uptake rate of 3251D at specific relative humidity levels are limited; processors are advised to verify moisture regain across shift changes using a Karl Fischer analyzer or a calibrated manometric moisture balance.
The primary difference between 3251D and the low-flow injection moulding grades 3001D and 3052D is the melt flow rate measured at 210°C/2.16 kg. Under ASTM D1238-23, the reported values are 22 g/10 min for 3001D, 14 g/10 min for 3052D, and 80 g/10 min for 3251D. The differential has practical consequences in conventional hydraulic injection moulding machines where the screw has a diameter of 35–50 mm and the tool contains thin-wall sections below 1.5 mm. The high-flow grade moves the flow-length/wall-thickness balance upward, allowing lower injection pressure demand or shorter fill time under identical cavity conditions.
| Grade | Nominal Melt Flow Rate at 210°C/2.16 kg | Tensile Yield Strength | Notched Izod Impact | HDT at 0.45 MPa |
|---|---|---|---|---|
| Ingeo 3052D | 14 g/10 min | 60 MPa | 16 J/m | 55°C |
| Ingeo 3001D | 22 g/10 min | 60 MPa | 16 J/m | 55°C |
| Ingeo 3251D | 80 g/10 min | 60 MPa | 16 J/m | 55°C |
The relative melt flow rate values indicate 3.6× fluidity versus 3001D and 5.7× versus 3052D. Since tensile yield strength, notched Izod impact, and HDT values remain approximately unchanged in the published data, substitution should not be treated as a mechanical-property upgrade. The change is a processing change. Processors moving from 3052D to 3251D should first evaluate the lower end of the manufacturer-published melt-temperature range to avoid excessive drool at the nozzle and uncontrolled decompression after plastication. Published data for this specific configuration is limited; the effect must be confirmed on the production tool because gate geometry, hot-runner manifold temperature, and colourant chemistry alter melt viscosity and heat history independently of resin grade.
Application suitability is concentrated in short-cycle, thin-wall articles: food-service utensils, cosmetic closures, transparent packaging inserts, and technical housings that remain below the 50°C threshold defined by the 1.82 MPa HDT value. These applications exploit the 80 g/10 min melt flow rate without demanding continuous heat resistance. The resin is not formulated for hot-fill containers, dishwasher-safe components, or under-hood automotive parts. Components requiring dimensional stability above 55°C under the 0.45 MPa load condition should be considered for annealing, nucleating-agent modification, or replacement with a heat-tolerant PLA compound. For transparent amorphous articles, the injection mould is commonly maintained at 25–30°C; increasing the mould temperature above 60°C promotes crystallization but extends cycle time and increases shrinkage non-uniformity unless the tooling is designed for PLA-specific crystallization behaviour. Published data for 3251D under high mould-temperature crystallization is limited.
Barrel temperature control must balance fill pressure against residence-time degradation. PLA undergoes random chain scission when held at elevated melt temperature longer than necessary, and the elevated melt flow rate of 3251D makes the resin sensitive to hot-spot residence in the screw antechamber and to shear heating in the check-ring channel. The recommended melt-temperature window for Ingeo injection grades is generally 200–230°C, with the nozzle set near the lower end unless the tool has extremely thin wall sections. Screw rotation speed and backpressure should be set to avoid frictional heat that drives the melt beyond the published envelope. Overly aggressive plastication can create unstable check-ring closure and shot weight variation because the melt viscosity is already low relative to 3052D. Published data for this specific configuration is limited; production trials on the target mould are required.
Moisture and hydrolytic degradation constitute the clearest operational boundary. Exposure to residual moisture above 250 ppm shifts the effective melt flow rate upward through chain scission and produces a resin that no longer corresponds to the published property set. The resulting surface defects are often misdiagnosed as venting or mould-release issues, but the root cause is hydrolytic molecular weight loss in the barrel. Regrind reuse follows the same mechanism: heat history reduces molecular weight and increases the likely moisture burden. The manufacturer-published data do not include a maximum regrind percentage for 3251D; published data for this specific configuration is limited, and production-scale regrind trials should include melt flow and notched Izod testing after each generation.
The grade is not chemically compatible with strong alkaline fillers or with additives that catalyze hydrolysis. Contact with Lewis acid catalysts or with zinc-stearate-based lubricants should be evaluated before use if regrind streams are not fully characterized.
Incoming quality control for 3251D should not rely solely on pellet appearance or hopper temperature. The melt flow rate should be measured under ASTM D1238-23 Procedure A at 210°C/2.16 kg, and the result should be compared with the 80 g/10 min manufacturer-published value. A parallel Karl Fischer moisture analysis on pellet samples from the feed throat, not only from sealed boxes, is required because moisture can be reabsorbed after opening. Differential scanning calorimetry at a heating rate of 10°C/min can be used to track glass transition and melting endotherm shifts; the glass transition is observed near 55–60°C for PLA of this family, but published data for this specific configuration is limited. Batch-to-batch variation in colour and optical haze is typically low but should be checked with injection-moulded plaques using ASTM D1003-13.
Regulatory status for food-contact applications remains a final-article responsibility. The base Ingeo PLA chemistry is generally supported under EU Regulation 10/2011 and FDA 21 CFR 175.300 when used within specified end-use conditions, but the presence of colourants, nucleating agents, impact modifiers, or recycled content can alter the compliance profile. Industrial compostability of the base resin may be certified under EN 13432 or ASTM D6400; however, certification applies to the finished article and not to the resin in isolation. Users must verify the final product against the intended disposal route and the relevant national legislation. No statement in this document is a regulatory certification for 3251D.