| HS Code | 537526 |
| Productname | Polylactic Acid (PLA) REVODE701 |
| Chemicalname | Polylactic acid |
| Casnumber | 26100-51-6 |
| Appearance | White to off-white pellets |
| Density | 1.24-1.25 g/cm3 |
| Meltflowrate | 10-20 g/10 min at 190°C/2.16 kg |
| Meltingpoint | 160-170°C |
| Glasstransitiontemperature | 55-60°C |
| Tensilestrength | 50-60 MPa |
| Elongationatbreak | 5-10% |
| Flexuralmodulus | 3000-3500 MPa |
| Impactstrength | 2-5 kJ/m2 |
| Moisturecontent | ≤0.5% |
| Vicatsofteningpoint | 55-60°C |
| Heatdeflectiontemperature | 50-55°C |
| Biodegradability | Compostable |
| Renewablecontent | Plant-based |
| Processingmethod | Injection molding |
As an accredited Polylactic Acid (PLA) REVODE701 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Typically, Polylactic Acid (PLA) REVODE701 packaging consists of 25 kg net-weight moisture-barrier paper bags, palletized and shrink-wrapped for industrial shipping. |
| Container Loading (20′ FCL) | 20′ FCL container loading of Polylactic Acid (PLA) REVODE701: palletized 25 kg bags, shrink-wrapped, securely stowed for sea transport. |
| Shipping | Polylactic Acid (PLA) REVODE701 is non-hazardous and not regulated for transport by DOT, IMDG, or IATA. Ship as general cargo in sealed 25 kg bags or cartons on pallets. Keep dry, cool, and away from direct sunlight and moisture. No special UN number, hazard class, or labeling required. |
| Storage | Store Polylactic Acid (PLA) REVODE701 in a cool, dry, well-ventilated area, away from direct sunlight, heat, and ignition sources. Keep bags or containers tightly sealed to prevent moisture absorption. Maintain relative humidity below 50% and temperature below 30°C. Avoid contact with strong acids, bases, and oxidizing agents. Use within recommended shelf life; rotate stock. Ensure good housekeeping and label containers clearly. |
| Shelf Life | REVODE701 PLA shelf life is about 12 months when kept in original sealed packaging, cool, dry, and protected from moisture and heat. |
Injection molding of REVODE701 for disposable food-contact cutlery is run on reciprocating-screw machines with screw L/D ratio 20:1 to 24:1 and compression ratio 2.5:1. The grade is pre-dried in a desiccant dryer at 80 °C for 4 h to a dew point of −40 °C, after which pellet moisture content should remain below 250 ppm. Melt temperature is maintained between 190 °C and 210 °C; residence time above 210 °C is held under 8 min to prevent lactide reformation and melt viscosity loss. Mold temperature is set at 20–30 °C using chilled water. Formulation addition ratios for knife, fork, and spoon production start with REVODE701 at 97.0–99.5 wt%, a nucleating agent loading not exceeding 0.5 wt%, an external lubricant such as erucamide at 0.2–0.3 wt%, and a bio-based impact modifier at 0–5.0 wt% when bend resistance above 120° without fracture is specified. Compliance for food-contact cutlery is evaluated under FDA 21 CFR 177.1520, Regulation (EC) No 10/2011 with overall migration limits set in Annex II as 10 mg/dm², and GB 4806.7-2016 where applicable; specific migration of lactic acid and tin-based catalyst residues should be verified by EN 1186-1:2002 and GB 31604.1-2015. Finished article types produced on this line include 150–200 mm injection-molded forks, spoons, knives, combined spork units, and coffee stirrers.
| Jurisdiction | Standard/Regulation | Test Method | Requirement |
|---|---|---|---|
| United States | FDA 21 CFR 177.1520 | Extraction testing per regulation | Finished article complies with lactic-acid polymer specifications and end-use extraction limits |
| European Union | Regulation (EC) No 10/2011 | EN 1186-1:2002 overall migration | 10 mg/dm² overall migration limit |
| China | GB 4806.7-2016 | GB 31604.1-2015 | Migration limits for food-contact plastics |
| Compostability | EN 13432:2000 / ASTM D6400-19 | Biodegradation and disintegration per standard | 90% biodegradation in 180 days; disintegration 90% in 12 weeks |
Substituting REVODE701 for SAN and PP in cosmetic jar bodies and closure sets alters the holding-pressure profile because of the resin’s lower thermal conductivity and higher melt compressibility. Molding is performed on all-electric injection machines with clamp force from 80 t to 150 t, using valve-gated hot runners or cold sprue systems; barrel temperatures are staged from 165 °C in the rear zone to 205 °C at the nozzle. In multi-cavity closure tools with 16–32 cavities, injection velocity is staged to avoid jetting, and pack pressure is held at 55–75 MPa for a duration determined by gate freeze, normally 1.5–2.5 s after velocity-to-pressure switch. Formulation addition ratios are REVODE701 96.5–99.0 wt%, clarifying agent 0–1.0 wt%, silicone-based release additive 0.1–0.3 wt%, and bio-based color masterbatch 1.0–3.0 wt%. Drying uses desiccant equipment at 80 °C for 4 h to a dew point of −40 °C; melt temperature is held at 195 ± 5 °C; mold temperature is controlled at 25 °C with chilled water. Dimensional stabilization for 24 h at 23 °C/50% RH is applied before thread fit testing. Industry compliance standards include Regulation (EC) No 1223/2009 for cosmetic product safety, REACH Regulation (EC) No 1907/2006 Annex XVII, and FDA 21 CFR 174.5 for indirect food additive exposure where packaging contacts lip care or other cosmetic formulations; plasticizer exudation is evaluated by ISO 177:2016. Terminal finished parts include 15–100 mL cream jars, snap-fit closure shells, airless pump collars, and transparent inner sleeves.
In soil-contact horticultural applications, REVODE701 is melt-processed into vine clips, plant support rings, and greenhouse fasteners on general-purpose injection machines with shot capacity matched to the tool layout. Hydrolysis is the primary failure mode: if pellet moisture exceeds 400 ppm, melt flow index measured at 210 °C/2.16 kg under ISO 1133-1:2022 rises sharply, and part brittleness increases after outdoor exposure. Pre-drying at 80 °C for 4 h to below 250 ppm moisture is therefore a mandatory in-line checkpoint. The formulation addition ratio for outdoor clips comprises REVODE701 at 95.0–99.0 wt%, a UV stabilizer package at 0.5–1.5 wt%, mineral filler at 0–2.0 wt% for flexural modulus, and a biodegradable color masterbatch at 0.5–1.0 wt%. Injection is run at melt temperature 180–200 °C, mold temperature 15–25 °C, and parts are ejected after the surface temperature falls below 40 °C to prevent gate deformation. Compliance standards in this segment are primarily EN 13432:2000 or ASTM D6400-19 for compostability claims; for non-packaging articles, ISO 17088:2012 is often applied. Field-service durability is assessed by accelerated weathering under ISO 4892-2:2013 method A. Terminal products include 20–80 mm vine clips, adjustable plant ties, root-ball pins, and seedling spacing clips.
For small-format toy sprues where general-purpose polystyrene would otherwise be selected, REVODE701 is injected in multi-cavity cold-runner tools with part weights from 2 g to 45 g. The low melt elasticity of PLA requires a faster injection velocity of 80–120 mm/s and a holding pressure of 60–80 MPa to prevent sink marks at rib intersections. Formulation addition ratios are REVODE701 98.0–99.5 wt%, color masterbatch 0.5–2.0 wt%, and anti-scratch additive 0–0.5 wt%; plasticizer is excluded because plasticizer migration causes failure of EN 71-3:2019+A1:2021 soluble-element limits. The production process includes pre-drying at 80 °C for 4 h, melt temperature 190–205 °C, mold temperature 20 °C, and post-mold dimensional inspection after 24 h at 23 °C/50% RH. Compliance standards are Toy Safety Directive 2009/48/EC, EN 71-1 mechanical safety, EN 71-3:2019+A1:2021 migration of elements, and REACH Annex XVII entries 51 and 52 for phthalate restrictions. Terminal finished component types include toy building block inserts, model sprue parts, board game tokens, and construction set connectors. A documented thermal limitation applies: continuous exposure above 50 °C can cause distortion; parts intended for hot environments are tested under ISO 75-2:2013 method A at 0.45 MPa.
Transparent desk trays, pencil cups, and index card boxes are molded from REVODE701 with nominal wall thickness of 2.0–3.5 mm; the main processing defect observed in production is sink formation at rib intersections, which requires holding pressure to be maintained until gate freeze. In this segment, REVODE701 is used at 97.5–99.0 wt%, optical brightener at 0–0.3 wt%, and mold release agent at 0.2–0.5 wt%. The downstream process comprises pre-drying at 80 °C for 4 h, injection at 190–205 °C, mold cooling at 20 °C, and post-molding annealing at 60 °C for 2 h only when dimensional stability above 45 °C is specified. Regulatory requirements are limited; REACH Regulation (EC) No 1907/2006 Annex XVII applies, and for children’s stationery the accessible printed surface is tested under EN 71-3:2019+A1:2021. Finished product types include A4 filing trays, desk organizers, business card holders, and drawer divider components. Published data for the specific creep behavior of REVODE701 under long-term desk loading is limited, so load-bearing ribs are validated by applying 5 kg static load for 72 h at 23 °C using ISO 899-1:2017.
Thin-wall food-container lids molded from REVODE701 at 0.5 mm nominal thickness are produced on high-speed injection machines with accumulator-assisted hydraulic or all-electric drives and clamp force up to 250 t. The main process conflict is shear heating: fast injection produces melt-temperature overshoot above 210 °C at the gate, causing lactide regeneration and gate blush, while slow injection causes short shots. Injection velocity is therefore set at 120–180 mm/s, with a velocity-to-pressure switch at 95–98% of fill volume; holding pressure is held at 70–90 MPa until the gate freezes, typically 1.0–2.0 s. Formulation addition ratios are REVODE701 98.0–99.0 wt%, nucleating agent 0.3–0.5 wt%, and slip agent 0.1–0.3 wt%; no impact modifier is used because it raises haze in the lid. Drying is performed at 80 °C for 4 h to below 250 ppm moisture. Mold temperature is controlled at 15–25 °C, and cooling time is limited to 8–12 s; post-mold shrinkage is measured after 24 h at 23 °C/50% RH and should remain below 0.5% in the flow direction. Compliance for this segment follows the same food-contact framework as cutlery: FDA 21 CFR 177.1520, Regulation (EC) No 10/2011 with overall migration limit 10 mg/dm², and GB 4806.7-2016 where applicable. Terminal finished product types include cold-drink lids, salad container lids, deli container lids, and tamper-evident clamshell hinge lids. Published data for the specific shrinkage behavior of REVODE701 at 0.5 mm wall stock is limited; mold shrinkage should be confirmed by trial runs because gate geometry and cooling channel layout exert more influence than the resin’s nominal datasheet shrinkage value.
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Polylactic Acid (PLA) REVODE701 is a medium-flow thermoplastic polyester derived from ring-opening polymerization of L-lactide. The resin is supplied as cylindrical pellets and is positioned for injection molding and short-cycle thermoforming where thin-wall fill, optical clarity, and a narrow thermal history are required. Published D-isomer content data for this specific grade is limited. Solid density is 1.24 g/cm³ per ISO 1183-1:2019, and melt density at 230 °C is approximately 1.10 g/cm³. Melt flow index determined at 210 °C with a 2.16 kg piston load per ISO 1133-1:2022 is commonly reported in the range 10–15 g/10 min. For injection-molded plaques with 2 mm thickness, total luminous transmittance exceeds 90% and haze is typically below 2% when measured according to ASTM D1003-21. Moisture content above 250 ppm is considered a processing defect threshold because the ester backbone is hydrolytically labile in the melt.
The values listed below are typical injection-molding PLA values for REVODE701 and should be treated as supplier technical data rather than guaranteed lot release minima. Because the polymer is hygroscopic, tensile strength and elongation are particularly sensitive to moisture before melt processing.
| Property | Value | Standard |
|---|---|---|
| Melt flow index at 210 °C/2.16 kg | 10–15 g/10 min | ISO 1133-1:2022 |
| Solid density | 1.24 g/cm³ | ISO 1183-1:2019 |
| Tensile strength at yield | 60–65 MPa | ISO 527-2:2012 |
| Tensile modulus | 3500 MPa | ISO 527-2:2012 |
| Elongation at break | 3–5% | ISO 527-2:2012 |
| Flexural strength | 90 MPa | ISO 178:2019 |
| Flexural modulus | 3600 MPa | ISO 178:2019 |
| Notched Izod impact | 2.5–3.5 kJ/m² | ISO 180/A:2019 |
| Heat deflection temperature at 0.45 MPa | 55–60 °C | ISO 75-2/B:2013 |
| Vicat softening temperature | 58–62 °C | ISO 306:2022 |
| Luminous transmittance at 2 mm | >90% | ASTM D1003-21 |
| Moisture content after drying | <250 ppm | ISO 15512:2019 |
Thermal analysis by differential scanning calorimetry according to ISO 11357-2:2020 and ISO 11357-3:2018 typically reveals a glass transition at 58–60 °C, a cold crystallization exotherm at 95–110 °C, and a melting endotherm at 170–180 °C. These transitions define the annealing window for post-mold crystallization.
Prior to melting, REVODE701 is dried in a desiccant-bed dryer at 80 °C for 4 h or until the outlet air attains a dew point of -40 °C. Moisture content is verified by Karl Fischer titration per ISO 15512:2019; the target is below 250 ppm. At ambient relative humidity above 60%, pre-drying is mandatory, and open pellet transfer to the machine throat should be limited to 15 min because PLA re-absorbs surface moisture rapidly. Undried resin produces splay, gas streaks, and weakened weld lines through water-induced ester bond cleavage that reduces molecular weight and increases melt flow index during barrel residence.
Drying equipment should deliver air at a superficial velocity of approximately 0.05 m/s with an airflow of 1.0–1.5 m³/h per kg/h throughput. Hopper capacity should provide at least 4 h residence at maximum throughput. Oversized hoppers with low material level can create funnel flow, causing intermittent moisture spikes and batch-to-batch processing variance. In production-scale handling, pellets stored at 60% RH in damaged moisture-barrier packaging can exceed 0.2 wt% moisture within 24 h.
Additives with primary or secondary amine functionality should be avoided because they can catalyze hydrolytic chain scission at processing temperatures. Acid-functional lubricants should be evaluated for melt pH shift. If regrind is used, the regrind fraction should be limited to 20 wt% and dried together with virgin pellets because reprocessing consumes stabilizer and accumulates lactide. Residence times above 230 °C should be avoided because thermal depolymerization regenerates lactide, which can deposit on tool and vent surfaces as a white crystalline film.
Barrel temperature profiles for injection molding typically proceed from 170 °C in the feed zone to 200 °C at the nozzle, with melt temperature held below 210 °C. Mold temperatures between 25 °C and 40 °C favor a transparent amorphous surface and short cycle times. Injection pressures of 80–120 MPa are common for thin-wall cavities down to 1.0 mm wall thickness on hydraulic machines with clamping force from 600 kN to 1,000 kN. Screw backpressure is limited to 0.5–1.0 MPa to avoid viscous heating, and total residence time in the barrel is held below 300 s. The practical processing window between cold crystallization and thermal degradation is narrow; melt temperatures below 175 °C can raise viscosity through cold crystallization, while melt temperatures above 215 °C accelerate molecular weight loss and color shift. Hot runner systems should avoid stagnation zones and should restrict melt temperature overshoot to 5 °C above setpoint.
In capillary rheometry per ISO 11443:2021, PLA melts display pronounced shear-thinning. For medium-flow PLA at 210 °C, apparent shear viscosity typically falls from 300–500 Pa·s at 100 s⁻¹ to 60–100 Pa·s at 1,000 s⁻¹. This behavior permits thin-wall filling at moderate injection pressure but limits melt strength in profile extrusion and blow molding. Tooling with polished cores should use draft angles of 0.5–1.0° because amorphous PLA has lower elastic recovery than polypropylene and can gall on highly polished surfaces.
Post-mold dimensional stability depends on as-molded crystallinity. Without annealing, amorphous parts can shrink 0.2–0.5% during the first 48 h and may deform under continuous service above 50 °C. For applications requiring higher heat resistance, parts are annealed at 110 °C for 30 min; this raises heat deflection temperature toward 120–140 °C under 0.45 MPa per ISO 75-2/B:2013. Annealing increases density and reduces transparency, so dimensional tolerances and cycle time must be revalidated. Unannealed REVODE701 should not be specified for hot-fill service above 60 °C unless part geometry and wall thickness are confirmed by creep testing.
Food-contact applications require grade-specific documentation. In the European Union, PLA is assessed under Commission Regulation (EU) No 10/2011; compliance claims should list overall migration values obtained according to EN 1186-1:2002 and specific migration tests in the intended food simulant. In the United States, PLA food-contact status is generally established through Food Contact Notifications rather than solely through a single section of 21 CFR. The supplier certificate should state the applicable FCN number, permitted food types, and contact temperature conditions. Specific migration of lactide and low-molecular-weight oligomers should be assessed for fatty food simulants at elevated temperature because PLA hydrolysis products may migrate.
| Regime | Scope | Verification |
|---|---|---|
| EU 10/2011 | Food-contact plastics | Overall migration per EN 1186-1:2002; specific migration in food simulant |
| FDA | Food-contact status | Supplier Food Contact Notification number and conditions of use |
| REACH 1907/2006/EC | Substances of very high concern | Supplier declaration; analytical confirmation for listed substances |
| RoHS 2011/65/EU + 2015/863 | Restricted substances | IEC 62321-5:2013; IEC 62321-7-1:2015 |
| ASTM D6866-22 | Biobased carbon content | Radiocarbon analysis if biobased claims are documented |
Shelf-storage of REVODE701 pellets requires sealed moisture-barrier bags at 15–30 °C and protection from direct sunlight. Partially used bags should be resealed with desiccant. If a bag has been opened for 30 min at 50% RH, the next processing lot should be dried again before melt processing.
In relation to high-viscosity PLA film and extrusion grades, REVODE701 exhibits lower melt tension and shorter capillary relaxation time; this is advantageous in thin-wall injection filling but limits bubble stability in blown film. In relation to nucleated high-heat PLA grades, REVODE701 has lower as-molded heat resistance unless post-mold annealing is specified. Compared with PBAT-modified PLA blends, REVODE701 shows higher tensile modulus and lower elongation at break; flexible packaging applications are therefore outside the recommended operational boundary. When compared with polyethylene terephthalate, REVODE701 has a lower melt processing temperature and lower solid density, but lower heat deflection temperature and greater hydrolytic sensitivity in melt handling. Published third-party comparative data for this specific REVODE701 configuration is limited; grade selection should be based on supplier batch certificates, application-specific rheological measurement, and tool trial results.